Journal
CHEMICAL SCIENCE
Volume 13, Issue 33, Pages 9678-9684Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc02090d
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Funding
- DST-Ramanujan fellowship [SB/S2/RJN-171/2017]
- CSIR India
- IIT Kharagpur
- Kyulux Inc.
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The solvent plays a crucial role in the photophysical properties of donor-acceptor based photocatalysts. The access to E vs. Z-allylic amines, depending on the solvent, was achieved through decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies were conducted to understand the role of the solvent in the reactivity and stereoselectivity of the vinylation reactions.
The solvent plays an important role in the photophysical properties of donor-acceptor based photocatalysts. The solvent-dependent access to E vs. Z-allylic amines was achieved via decarboxylative vinylation of amino acids with vinyl sulfones. Detailed experimental studies have been conducted to understand the role of the solvent in the reactivity and stereoselectivity of the vinylation reactions.
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