4.7 Article

Explicit solvent effects on macromolecular interactions from a solvent-augmented contact value theorem

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Summary: In this study, we propose an electrolyte model composed of solvent molecules and salt ions, and investigate the salt-induced dielectric decrement by considering salt-solvent correlations. By using a virial expansion to treat the salt charges, we are able to explicitly include the many-body salt-solvent interactions and explain the experimentally observed linear decay of electrolyte permittivity with added dilute salt. Our findings indicate that the reduction of solvent permittivity is caused by the salt screening of polarization charges, which suppresses the dielectric response of the solvent. We also demonstrate that our model can accurately reproduce various experimental trends, such as the attenuation of electrolyte permittivity with rising temperature and its intensification with salt valency.

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