Journal
DALTON TRANSACTIONS
Volume 51, Issue 35, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt01462a
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Funding
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry, and Energy (MOTIE) of the Republic of Korea [20202020800330]
- Institutional Research Program of KRICT [KK2210-00]
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In this study, molecular trimeric ruthenium carboxylate clusters (Ru-3 clusters) were successfully introduced into the pore channels of mesoporous metal-organic framework chromium terephthalate [MIL-101(Cr)] using a two-step post-synthetic strategy. The catalytic activity of the immobilized Ru-3 clusters in the pore channels was significantly enhanced compared to the bulk counterpart.
Molecular trimeric ruthenium carboxylate clusters (Ru-3 clusters) have been introduced into the pore channels of mesoporous metal-organic framework chromium terephthalate [MIL-101(Cr)] by employing a facile two-step post-synthetic strategy in which diamine hooks anchored on the framework metal nodes of the MOF are used to covalently immobilize the Ru-3 clusters. The catalytic activity of the isolated Ru-3 clusters in the pore channels of the MOF was significantly improved compared to the bulk counterpart.
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