4.7 Article

Seeded-growth self-assembled polymerization of a ferrocene-bearing palladium(ii)-terpyridyl bimetallic complex

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 71, Pages 9878-9881

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02375j

Keywords

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Funding

  1. Science, Technology and Innovation Committee of Shenzhen Municipality [JCYJ2018050 7183413211]
  2. National Natural Science Foundation of China [52073242, 22075184]
  3. RGC Senior Research Fellowship Scheme [SRFS2021-5S01]
  4. Hong Kong Research Grants Council [PolyU153062/18P]
  5. Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials [2019B121205002]
  6. Miss Clarea Au for the Endowed Professorship in Energy [847S]

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A new bimetallic complex with a palladium core containing a 4'-ferrocenyl-(2,2':6',2''-terpyridine) and a polyethylene glycol-based pyridine ligand is applied for the first time in seeded-growth self-assembled supramolecular polymerization, resulting in nanoribbons with controllable lengths following a first-order reaction kinetics.
A new bimetallic complex containing a 4 '-ferrocenyl-(2,2 ':6 ',2 ''-terpyridine)palladium core with polyethylene glycol-based pyridine is applied in seeded-growth self-assembled supramolecular polymerization, which affords nanoribbons with controllable lengths and the process follows a first-order reaction kinetics. This approach is successfully demonstrated for a bimetallic organic complex for the first time.

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