3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP): a versatile CO2-derived lactone platform for polymer synthesis

3-Ethyl-6-vinyltetrahydro-2H-pyran-2-one (EVP) is a CO2-derived lactone synthesized via Pd-catalyzed telomerization of butadiene. As EVP is 28.9% by weight CO2, it has received significant recent attention as an intermediary for the synthesis of high CO2-content polymers. This article provides an overview of strategies for the polymerization of EVP to a wide variety of polymer structures, ranging from radical polymerizations to ring-opening polymerizations, that each take unique advantage of the highly functionalized lactone.

Automated summary

This article provides an overview of strategies for the polymerization of EVP to various polymer structures, utilizing the highly functionalized lactone, including radical polymerizations and ring-opening polymerizations.