Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 72, Pages 10091-10094Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc04028j
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Funding
- Marsden Fund Council [MFP-VUW2020]
- EPSRC [EP/R020752]
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The corresponding Al(mu-O)M complexes were isolated by the reaction of compounds containing Al-Mg and Al-Zn bonds with N2O. Electronic structure analysis revealed mainly ionic Al-O and O-M bonds in these complexes, featuring an anionic mu-oxo centre. The reaction with CO2 confirmed that these species correspond to the proposed intermediates in the formation of mu-carbonate compounds.
The reaction of compounds containing Al-Mg and Al-Zn bonds with N2O enabled isolation of the corresponding Al(mu-O)M complexes. Electronic structure analysis identified largely ionic Al-O and O-M bonds, featuring an anionic mu-oxo centre. Reaction with CO2 confirmed that these species correspond to the proposed intermediates in the formation of mu-carbonate compounds.
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