Journal
ARKIVOC
Volume -, Issue -, Pages 27-56Publisher
ARKAT USA INC
DOI: 10.24820/ark.5550190.p011.800
Keywords
Hypervalent compounds; iodine (V); catalysis; oxidation
Categories
Funding
- J C Bose University of Science and Technology, YMCA [R&D/SG/2020-21/166]
- DST - Haryana [HSCSIT/RD/163]
- JSPS KAKENHI [18H02014, 19K05466]
- JST CREST [JPMJCR20R1]
- Ritsumeikan Global Innovation Research Organization (R -GIRO) project
- National Science Foundation [CHE-1759798]
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The chemistry of hypervalent iodine compounds, both as stoichiometric reagents and catalysts, has been extensively studied in recent decades. Hypervalent iodine (V)-catalyzed reactions have proven to be versatile systems for various oxidative transformations. This review discusses the versatility of hypervalent iodine (V)-catalyzed reactions in detail, highlighting the oxidation of various substrates using catalytic amounts of o-iodoxybenzoic acid, modified IBX derivatives, o-iodoxybenzenesulfonic acid, recyclable iodine (V), and non-cyclic/pseudocyclic iodine (V) compounds.
The chemistry of hypervalent iodine compounds has been widely recognized in the synthetic community. The utilization of hypervalent iodine compounds as stoichiometric reagents as well as catalysts has tremendously been studied in recent decades. Hypervalent iodine (V)-catalyzed reactions are proven to be versatile catalytic systems to access various oxidative transformations. In this review, the versatility of hypervalent iodine (V) -catalyzed reactions have been discussed in detail. This review highlights the oxidation of various substrates using catalytic amounts of o-iodoxybenzoic acid (IBX), modified IBX derivatives, o-iodoxybenzenesulfonic acid (IBS), recyclable iodine (V), and non-cyclic/pseudocyclic iodine (V) compounds.
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