Recent advances in the oxidative esterification of 5-hydroxymethylfurfural to furan-2,5-dimethylcarboxylate

5-Hydroxymethylfurfural (HMF) as an important versatile compound derived from renewable biomass has gained great significance in both industry and academia. The oxidative esterification product of HMF, furan-2,5-dimethylcarboxylate (FDMC), is considered to be a good candidate for the replacement of 2,5-furan dicarboxylic acid (FDCA) as a bioplastics synthon. However, HMF oxidative esterification to FDMC has not been comprehensively summarized to date. Recent studies on the production of FDMC from HMF via various catalytic approaches including the use of noble or non-noble metal catalysts in a base or base free environment have been discussed. The approach of the continuous flow regime for the preparation of FDMC is likewise summarized. Furthermore, the perspective toward industrialization of HMF oxidative esterification to FDMC in a more green, simple, efficient and economical way has also been proposed.

Automated summary

This article provides a comprehensive review on the oxidative esterification of 5-Hydroxymethylfurfural (HMF) to furan-2,5-dimethylcarboxylate (FDMC), which is considered as a potential replacement for 2,5-furan dicarboxylic acid (FDCA) in bioplastics synthesis. The recent progress in various catalytic approaches, including the use of noble or non-noble metal catalysts in different reaction environments, is discussed. The continuous flow regime for FDMC preparation is also summarized. Furthermore, the perspective towards industrialization of HMF oxidative esterification to FDMC in a more sustainable, efficient, and economical way is proposed.