4.6 Review

Thermal, chemical, electrochemical, radiolytic and biological stability of ionic liquids and deep eutectic solvents

Journal

NEW JOURNAL OF CHEMISTRY
Volume 46, Issue 37, Pages 17640-17668

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj03148e

Keywords

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Funding

  1. National Natural Science Foundation of China [22103030, 22073112]
  2. Special Project for the Cultivation of Scientific and Technological Innovation Ability of College and Middle School Students in Hebei Province [22E50480D]
  3. Open Fund of Hebei Biomass Carbon Materials and Application Technology Innovation Center [SG2021003]

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Ionic liquids (ILs) and deep eutectic solvents (DESs) are novel solvents with high tunability and wide sustainability and stability for industrial applications. This comprehensive review explores the thermal, chemical, electrochemical, radiolytic, and biological stability of ILs and DESs, aiming to provide guidance for the design of more stable ILs and DESs.
Ionic liquids (ILs) and deep eutectic solvents (DESs) are regarded as two types of novel solvents with high tunability, which exist in the liquid state in a wide temperature range. The sustainability of ILs and DESs enable their wide utilization as solvents, absorbents, electrolytes, surfactants, catalysts, lubricants and photosensitizers. Additionally, the stability of ILs and DESs is necessary for their application in industry. However, not all ILs and DESs are sufficiently stable. Herein, we present a comprehensive and systematic review on the thermal, chemical, electrochemical, radiolytic and biological stability of ILs and DESs. This can provide a guide for the better design of ILs and DESs with higher stability for industrial applications.

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