Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 10, Issue 38, Pages 20375-20385Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ta04966j
Keywords
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Funding
- National Natural Science Foundation of China [52162037]
- Natural Science Foundation of Yunnan Province [202201AT070041]
- Natural Science Foundation of Hunan Province [2021JJ30797]
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Charging electrochemical devices by light irradiation can result in significant capacitance enhancements, thereby potentially revolutionizing energy-storage technologies.
Charging electrochemical devices by light irradiation may bring an essential change in energy-storage technologies. Herein, nickel copper mixed oxide (NiCuOx)-based bifunctional photoelectrodes for integrated energy conversion and storage were developed to achieve significant capacitance enhancements by a photocharging process. NiCuOx nanosheets have been directly grown on carbon cloth (CC) by a simple electrodeposition/annealing method. NiO/CuOx heterojunctions have been formed in the CC@NiCuOx nanosheet structures, which presented an intimate interfacial contact, endowing the materials with bifunctional properties for realizing photoenergy conversion and electrochemical charge storage simultaneously. When used as three-electrode supercapacitors, the as-prepared CC@NiCuOx photoelectrodes demonstrated a maximum specific capacitance of 2937 mF cm(-2) under light irradiation, corresponding to 17.5% of enhancement compared to those delivered without light irradiation. Such a significant enhancement could be contributed by the in situ photocharging process, where the photo-generated holes from CuOx (including CuO and Cu2O) were transferred to neighboring NiO and then promoted the oxidation reactions of NiO. This work has provided a tentative study to show how photo-generated charge carriers can promote electrochemical charge storage.
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