Chemical functionalization of composite surfaces for improved structural bonded repairs

In terms of lightweight design, aerodynamics and structural integrity, bonded repairs represent the preferred approach for repairing composite structures in aircraft applications. In this work the influence of crucial surface parameters including roughness, polarity and chemical composition on the performance of bonded repairs is studied. Besides mechanical and physical interactions, the study aims at the surface modification of carbon-fiber reinforced polymers (CFRP) to tailor chemical interactions with the adhesive. Reactive epoxy and mercapto derivatives are attached onto the CFRP surface by a 2-step functionalization route to ensure optimized adhesion and covalent bonding to epoxy-based adhesives. The performance of bonded coupon joints is determined by single lap shear tests (tensile-shear loading) and fracture mechanical tests (mode I loading). The results give evidence that chemical interactions play a key role in the quality of bonded repair systems. By controlling the chemical surface properties improved bond strength, homogenous crack growth and cohesive failure patterns are achieved. (C) 2014 Elsevier Ltd. All rights reserved.