Journal
DALTON TRANSACTIONS
Volume 51, Issue 39, Pages 15128-15132Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt02554j
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Funding
- Hellenic Foundation for Research and Innovation (H.F.R.I.) [400]
- Leverhulme Trust [RPG-2021-176]
- European Union Horizon 2020 research and innovation programme under the Marie Skodowska-Curie [832488]
- Marie Curie Actions (MSCA) [832488] Funding Source: Marie Curie Actions (MSCA)
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The reaction between Co(OAc)(2)·4H(2)O and Hsal in a basic MeCN solution produces a hexadecanucleare wheel compound [Co-16(sal)(16)(OAc)(16)]·16MeCN (1.16MeCN) that exhibits ferromagnetic nearest neighbour exchange and pseudo-ca[ixarene character. Symmetry equivalent wheels self-assemble to form remarkable tubular networks of capsules in the extended structure.
Reaction of Co(OAc)(2)center dot 4H(2)O and Hsal in a basic MeCN solution affords the hexadecanudear wheel [Co-16(sal)(16)(OAc)(16)]center dot 16MeCN (1.16MeCN) that displays ferromagnetic nearest neighbour exchange and has pseudo-ca[ixarene character. Symmetry equivalent wheels self-assemble to form remarkable tubular networks of capsules in the extended structure.
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