4.6 Article

Visible light induced RAFT for asymmetric functionalization of silica mesopores

Journal

RSC ADVANCES
Volume 12, Issue 42, Pages 27109-27113

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra05422a

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Funding

  1. European Research Council (ERC) under the European Union [803758]
  2. Deutsche Forschungsgemeinschaft (DFG - German Research Foundation)
  3. Open Access Publishing Fund of Technical University of Darmstadt
  4. European Research Council (ERC) [803758] Funding Source: European Research Council (ERC)

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One key feature for bioinspired transport design through nanoscale pores is the nanolocal, asymmetric, and multifunctional nanopore functionalization. This study utilized a visible-light induced PET-RAFT polymerization technique to asymmetrically place polymer into mesoporous silica thin films, including designing asymmetric polymer sequences.
One key feature for bioinspired transport design through nanoscale pores is nanolocal, asymmetric as well as multifunctional nanopore functionalization. Here, we use a visible-light induced, controlled photo electron/energy transfer-reversible addition-fragmentation chain-transfer (PET-RAFT) polymerization for asymmetric polymer placement into mesoporous silica thin films including asymmetric polymer sequence design.

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