Journal
GREEN CHEMISTRY
Volume 24, Issue 20, Pages 7889-7893Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2gc02701a
Keywords
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Funding
- National Natural Science Foundation of China [22101054, 31900086]
- GDAS' Project of Science and Technology Development [2021GDASYL-20210103018]
- Zhejiang Provincial Natural Science Foundation [LQ22B020006]
- Jiaxing Public Welfare Research Program [2021AY10047]
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The combination of photocatalysis and biocatalysis has greatly advanced the development of novel synthetic strategies due to functional diversity and stereoselectivity. In this study, a one-pot cascade process combining photo-oxidative fluoridation and bio-reduction was described, which achieved enantiocomplementary vicinal fluoro alcohols with up to 87% isolated yield and 99% ee.
The combination of the catalytic power of photocatalysis and biocatalysis has greatly boosted the development of novel synthetic strategies due to its functional diversity and stereoselective specificity. Herein, we describe a one-pot cascade process that combined photo-oxidative fluoridation and bio-reduction to access enantiocomplementary vicinal fluoro alcohols with up to 87% isolated yield and 99% ee.
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