Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 24, Issue 43, Pages 26428-26437Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cp03160d
Keywords
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Funding
- CONICET [PIP 11220200102757CO]
- ANPCyT [PICT 2018-00924, 2019-02410]
- FWO [G079122N]
- Internal KU Leuven Funds [3E180972]
- CONICET
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This study demonstrates the presence of high kinetic barriers for internal conversion in anti-Kasha chromophores and provides guidelines for their design. The results highlight the importance of wavefunction symmetry in inhibiting dissipative IC and offer insights into the dissipation process at the atomistic level.
Internal conversion (IC) coupled to vibrational relaxation (VR) in molecular chromophores is a source of major energy losses in natural and artificial solar-to-chemical energy conversion schemes. The development of anti-Kasha chromophores, where dissipative IC channels are blocked, is a promising strategy to boost energy conversion efficiencies. In this contribution, we demonstrate the presence of an unusually high kinetic barrier for IC in [Ru(tpm)(bpy)(NCS)](+) (RuNCS), where tpm is tris(1-pyrazolyl)methane and bpy is 2,2 '-bipyridine, by means of an arsenal of temperature-dependent spectroscopic methods including nanosecond and femtosecond transient absorption spectroscopies. These studies are complemented with theoretical investigations, that provide a detailed atomistic description of the dissipation process, including the electronic structures of the excited states involved. The observed IC is mainly a hole reconfiguration within the octahedral t(2g) set of the Ru ion, with contributions from a Ru to NCS charge transfer. Thus, in a Marcus picture, inner and outer reorganizations contribute to the observed barrier. The results presented here show that wavefunction symmetry within a molecular chromophore can be exploited to inhibit dissipative IC. Finally, guidelines for the design of anti-Kasha chromophores that prevent dissipation in energy conversion schemes, based on minimum energy conical intersection calculations, are provided.
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