Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 9, Issue 23, Pages 6540-6546Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo01304e
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Funding
- National Natural Science Foundation of China [21801129]
- Natural Science Research Projects in Jiangsu Higher Education Institutions [18KJB150018]
- Nanjing Tech University [39837137]
- Guangdong Provincial Key Laboratory of Catalysis [2020B121201002]
- Soochow University [KJS1945]
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This study reveals a visible-light-induced stereo- and regioselective phosphorylation reaction, which can deliver synthetically and pharmaceutically appealing beta-phosphorylated enamides with broad substrate scopes and excellent functional group tolerance under transition-metal-free conditions.
A visible-light-induced stereo- and regioselective phosphorylation reaction of enamides with phosphine oxides has been disclosed, delivering synthetically and pharmaceutically appealing beta-phosphorylated enamides with broad substrate scopes and excellent functional group tolerance under transition-metal-free conditions.
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