Journal
CHEMICAL SCIENCE
Volume 13, Issue 41, Pages 12158-12163Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc02953g
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Funding
- National Science Foundation Division of Chemistry [CHE-1900266]
- University of Michigan
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Recent advances in synthetic chemistry have led to a resurgence in the development of methods for visible light-mediated radical generation. In this study, a photoactive ester based on a quinoline N-oxide core structure is reported, which acts as a strong oxidant in its excited state. The heteroaromatic N-oxide allows access to primary, secondary, and tertiary radical intermediates, and its application in the development of a photochemical Minisci alkylation is described.
Recent advances in synthetic chemistry have seen a resurgence in the development of methods for visible light-mediated radical generation. Herein, we report the development of a photoactive ester based on a quinoline N-oxide core structure, that provides a strong oxidant in its excited state. The heteroaromatic N-oxide provides access to primary, secondary, and tertiary radical intermediates, and its application toward the development of a photochemical Minisci alkylation is reported.
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