Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 20, Issue 44, Pages 8605-8609Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob01694j
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Funding
- Natural Science Foundation of Jiangsu Province [BK20200456]
- Fundamental Research Funds for the Central Universities [30922010808, AE89991/241]
- Nanjing University of Science and Technology (NJUST)
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An efficient Cu-catalysed protoboration of allenyl-Bdans has been developed, leading to moderate to high yields of β-boryl allyl-Bdans with excellent regio- and stereoselectivity.
An efficient Cu-catalysed protoboration of allenyl-Bdans is presented. Under the optimized reaction conditions, a series of allenyl-Bdans reacted smoothly with B(2)Pin(2) to afford beta-boryl allyl-Bdans in moderate to high yields with excellent regio- and stereoselectivity.
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