4.4 Article

Tribological Behavior of Titanium-Sintered Composites with Ring-Shaped TiN Dispersoids

Journal

LUBRICANTS
Volume 10, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/lubricants10100254

Keywords

core-shell structured TiN powder; ring-shaped TiN dispersion; tribological properties; titanium matrix composite; powder metallurgy; spark plasma sintering; friction coefficient; abrasive wear behavior; oil lubricant

Funding

  1. KAKENHI [20K05155]
  2. Light Metal Educational Foundation
  3. International Joint Research Promotion Program by Osaka University

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The study shows that the tribological properties of titanium matrix composites with ring-shaped TiN dispersoids are improved, leading to a significantly lower and more stable friction coefficient compared to pure titanium specimens. This enhancement is attributed to the ring-shaped, hard TiN dispersoids preventing adhesion phenomenon and improving oil film formability.
The wide applicability of titanium (Ti) has prompted the analysis to improve its mechanical strength through the addition of different alloying elements. Among these, Ti materials with pre-mixed pure Ti and titanium nitride (TiN) powders as the starting materials have exhibited improved mechanical properties and tribological performance. In this study, the tribological properties of Ti matrix composites with ring-shaped TiN dispersoids were evaluated. The materials were fabricated from pre-mixed pure Ti powder and core-shell structured Ti-(N) powder, which were prepared by heat treatment at 1273 K under N-2 gas. The tribological behavior of the Ti-TiN composites was studied by varying the applied load using a ball-on-disk wear test under oil lubrication conditions. The initial familiarity period of the Ti-TiN composites decreased. Subsequently, compared to the pure Ti specimen employed as a reference material, the friction coefficient was significantly lower and more stable. This is attributed to the ring-shaped, hard TiN dispersoids, which prevented the adhesion phenomenon and improved the oil film formability owing to the increase in microhardness and abrasive wear resistance of the nitrogen solid solution in the core region.

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