4.6 Article

Realization of a self-powered Cu2O ozone gas sensor through the lateral photovoltaic effect

Journal

JOURNAL OF MATERIALS CHEMISTRY C
Volume 10, Issue 43, Pages 16517-16523

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2tc03856k

Keywords

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Funding

  1. Ministry of Science and Technology of Taiwan [MOST 111-2221-E-260-010]

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This study presents a new self-powered gas sensor structure that utilizes the lateral photovoltaic effect for ozone detection. By using asymmetric light illumination, self-powering operation is achieved, allowing efficient gas sensing at room temperature.
Photovoltaic self-powered gas sensors are generally based on the device structure of a p-n photodiode, which requires two different electrodes on opposite sides of a heterojunction. However, the complicated structure is not compatible with planar circuit technology. A strategy of applying the lateral photovoltaic effect in detecting ozone (O-3) is proposed. By using asymmetric light illumination, self-powering operation is achieved without an external voltage. The recorded unbiased gas response is 88.6%, with a response/recovery time of 150/800 s after exposure to 5 ppm O-3 at room temperature. The Cu2O self-powered gas sensor has excellent selectivity to toxic gases, reliability under humidity and long-term stability to O-3. This study could provide new insights in the self-powered device domain.

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