Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 92, Pages 12871-12874Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc03745a
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Funding
- National Natural Science Foundation of China [21732006, 22071228, 51821006]
- Anhui Provincial Natural Science Foundation [BJ2060190102]
- Fundamental Research Funds for the Central Universities [WK3530000007]
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A cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes with propargylic carbonates under mild reaction conditions was developed, providing facile and efficient access to conjugated bisallenes with a broad range of functional groups.
A cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes with propargylic carbonates under mild reaction conditions was developed. This method provides facile and efficient access to conjugated bisallenes with a broad range of functional groups. Both aromatic and aliphatic 1,3-enynes can be utilized in this transformation to give the corresponding multi-substituted conjugated bisallenes.
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