☆ 4.6 Review

Metal-porphyrinic framework nanotechnologies in modern agricultural management

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Porphyrin-Containing MOFs and COFs as Heterogeneous Photosensitizers for Singlet Oxygen-Based Antimicrobial Nanodevices

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MOF-based multi-stimuli-responsive supramolecular nanoplatform equipped with macrocycle nanovalves for plant growth regulation

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Role of Zr6 Metal Nodes in Zr-Based Metal-Organic Frameworks for Catalytic Detoxification of Pesticides

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Summary: Pesticides have negative impacts on health and environment, but can be rapidly degraded using Zr-based metal-organic frameworks (MOFs), with MOFs based on six-connected Zr nodes showing the highest degradation efficiency. The study demonstrates the potential of MOFs as potent heterogeneous catalysts for organophosphate pesticide degradation.

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Functionalization of an iron-porphyrinic metal-organic framework with Bovine serum albumin for effective removal of organophosphate insecticides

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Summary: A multifunctional hybrid BSA-metal organic framework material was prepared for efficient removal of pesticide residues from water samples. The hybrid material showed high efficiency and suitable recyclability in removing methyl parathion and diazinon. In addition, the material with multiple binding sites exhibited enhanced adsorption activity compared to the metal organic framework alone.

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Summary: An efficient adsorbent was developed for the adsorption and removal of diazinon, utilizing a mixture of activated metal-organic framework and a binder. Various factors were optimized to achieve the best efficiency, resulting in a high adsorption capacity for diazinon.

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Adsorptive removal and visible-light photocatalytic degradation of large cationic and anionic dyes induced by air-bubbles in the presence of a magnetic porphyrinic metal-organic framework (Fe3O4@SiO2@PCN-222 (Fe))

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Water-stable Al-TCPP MOF nanosheets with hierarchical porous structure for removal of chlorantraniliprole in water

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Summary: This study successfully constructed a highly efficient and stable adsorbent, Al-TCPP nanosheets, for the removal of hazardous pesticide from water. The maximum adsorption capacity of chlorantraniliprole on Al-TCPP nanosheets was significantly higher than that of bulk crystals, indicating their potential for application in water treatment.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Fluorescence and electrochemical assay for bimodal detection of lead ions based on Metal-Organic framework nanosheets

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Summary: The study presents a bimodal strategy for signal-on, label-free lead ion detection in environmental samples using 2D-MOF nanosheets, which allows for both fluorescence and electrochemical detection with high sensitivity. The developed device is cost-effective, highly sensitive, and convenient to operate, showing promise as a reliable system for lead ion detection in environmental samples.

TALANTA (2021)

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Understanding disorder and linker deficiency in porphyrinic zirconium-based metal-organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221

Charlotte Koschnick et al.

Summary: The study found that PCN-221 is composed of Zr6O4(OH)(4) clusters in four distinct orientations within the unit cell, rather than Zr8O6 clusters as originally published. A disordered PCN-224 model is proposed as a unified model to understand the relationships between different MOFs. This work introduces a new perspective on network topology and disorder in Zr-MOFs.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Novel Lanthanide(III) Porphyrin-Based Metal-Organic Frameworks: Structure, Gas Adsorption, and Magnetic Properties

Nikolas Kiraly et al.

Summary: The study synthesized three porous coordination polymers of metal-porphyrin framework type and characterized their structure and gas adsorption properties. The results showed unique structural features and gas adsorption capabilities of these materials.

ACS OMEGA (2021)

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Article Green & Sustainable Science & Technology

Efficient elimination of chlorpyrifos via tailored macroporous membrane based on Al-MOF

Reda M. Abdelhameed et al.

Summary: Chlorpyrifos, an easily absorbed organophosphorus pesticide, was effectively removed using a novel adsorptive membrane composed of Al-metal organic framework@cellulose acetate. The membrane showed enhanced adsorptive capacity and fast removal rate for chlorpyrifos, with good recoverability and potential applications in environmental fields.

SUSTAINABLE MATERIALS AND TECHNOLOGIES (2021)

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Review Chemistry, Physical

Metal-organic frameworks for the generation of reactive oxygen species

Hudson A. Bicalho et al.

Summary: Reactive oxygen species (ROS) are highly reactive molecules derived from oxygen, with essential roles in biological processes and applications in industrial fields. Targeted production of ROS in cancerous cells for anti-cancer therapies has shown promising results, but developing catalysts that are easily synthesized, low-cost, nontoxic, and highly effective remains a challenge.

CHEMICAL PHYSICS REVIEWS (2021)

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Article Chemistry, Inorganic & Nuclear

Electrolytic synthesis of porphyrinic Zr-metal-organic frameworks with selective crystal topologies†

Keito Okada et al.

Summary: The thermodynamic and kinetic products of porphyrinic Zr-metal-organic frameworks were synthesized for the first time via an anodic dissolution approach. This is the first report of MOF polymorphs being controlled by electrolysis, with the selective formation of one polymorph requiring the presence of an amorphous component on the electrode during the initial reaction process.

DALTON TRANSACTIONS (2021)

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Review Engineering, Environmental

Molecularly imprinted polymers-based adsorption and photocatalytic approaches for mitigation of environmentally-hazardous pollutants A review

Ahmad Reza Bagheri et al.

Summary: The degradation of water quality due to accelerated urbanization and industrial expansion has raised concerns, leading to the development of novel mitigation methods. Among these methods, molecularly imprinted polymers (MIPs) have gained attention for their structural predictability, recognition specificity, and versatile applicability in removing emerging pollutants. Researchers are focusing on fabricating MIPs-based novel materials to effectively remove hazardous contaminants from environmental matrices.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Chemistry, Analytical

A luminescent method for detection of parathion based on zinc incorporated metal-organic framework

Liu Wang et al.

MICROCHEMICAL JOURNAL (2020)

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Article Chemistry, Analytical

Selective Sensing of Copper ions by Mesoporous Porphyrinic Metal-Organic Framework Nanoovals

Zhiyuan Xu et al.

ANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Porphyrin-based metal-organic framework and polyvinylchloride composites for fluorescence sensing of divalent cadmium ions in water

Hailey A. J. Hibbard et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Removal of Hg2+ heavy metal ion using a highly stable mesoporous porphyrinic zirconium metal-organic framework

Zahra Seyfi Hasankola et al.

INORGANICA CHIMICA ACTA (2020)

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Article Agriculture, Multidisciplinary

Developing a Novel Nanoscale Porphyrinic Metal-Organic Framework: A Bifunctional Platform with Sensitive Fluorescent Detection and Elimination of Nitenpyram in Agricultural Environment

Jintong Liu et al.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2020)

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Review Chemistry, Medicinal

Porphyrin-Based Metal-Organic Framework Compounds as Promising Nanomedicines in Photodynamic Therapy

Wenmei Yu et al.

CHEMMEDCHEM (2020)

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Review Chemistry, Physical

Catalytic Degradation of Nerve Agents

Agatino Zammataro et al.

CATALYSTS (2020)

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Article Chemistry, Analytical

Polydopamine coated zirconium metal-organic frameworks-based immunochromatographic assay for highly sensitive detection of deoxynivalenol

Rui Li et al.

ANALYTICA CHIMICA ACTA (2020)

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Article Chemistry, Multidisciplinary

A Porphyrinic Zirconium Metal-Organic Framework for Oxygen Reduction Reaction: Tailoring the Spacing between Active-Sites through Chain-Based Inorganic Building Units

Magdalena Ola Cichocka et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Environmental Sciences

Zr-MOF modified cotton fiber for pipette tip solid-phase extraction of four phenoxy herbicides in complex samples

Ying Su et al.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2020)

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Article Chemistry, Analytical

Ultrasensitive electrochemical aptasensor for ochratoxin A detection using AgPt bimetallic nanoparticles decorated iron-porphyrinic metal-organic framework for signal amplification

Jing Zhang et al.

SENSORS AND ACTUATORS B-CHEMICAL (2020)

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Article Materials Science, Multidisciplinary

Metal-organic frameworks as adsorbents for sequestering organic pollutants from wastewater

Kayode Adesina Adegoke et al.

MATERIALS CHEMISTRY AND PHYSICS (2020)

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Article Engineering, Biomedical

Biodegradable Metal-Organic Framework-Based Microrobots (MOFBOTs)

Anastasia Terzopoulou et al.

ADVANCED HEALTHCARE MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Zirconium-based metal-organic framework gels for selective luminescence sensing

Shujian Sun et al.

RSC ADVANCES (2020)

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Review Polymer Science

A Critical Review on Metal-Organic Frameworks and Their Composites as Advanced Materials for Adsorption and Photocatalytic Degradation of Emerging Organic Pollutants from Wastewater

Zakariyya Uba Zango et al.

POLYMERS (2020)

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Article Chemistry, Physical

Lifetime and diffusion distance of singlet oxygen in air under everyday atmospheric conditions

Kang-Kyun Wang et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2020)

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Article Nanoscience & Nanotechnology

Pore-Confined Silver Nanoparticles in a Porphyrinic Metal-Organic Framework for Electrochemical Nitrite Detection

Yi-Ching Wang et al.

ACS APPLIED NANO MATERIALS (2020)

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Article Biophysics

Single-step electrochemical sensing of ppt-level lead in leaf vegetables based on peroxidase-mimicking metal-organic framework

Xinai Zhang et al.

BIOSENSORS & BIOELECTRONICS (2020)

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Article Chemistry, Multidisciplinary

A stable nanoscaled Zr-MOF for the detection of toxic mycotoxin through a pH-modulated ratiometric luminescent switch

Xiaolei Guo et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Synthesis and Defect Characterization of Phase-Pure Zr-MOFs Based on Meso-tetracarboxyphenylporphyrin

Shaunak M. Shaikh et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Physical

Porphyrinic Metal-Organic Frameworks Installed with Bronsted Acid Sites for Efficient Tandem Semisynthesis of Artemisinin

Liang Feng et al.

ACS CATALYSIS (2019)

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Article Chemistry, Analytical

A novel electrochemical sensor based on 2D CuTCPP nanosheets and platelet ordered mesoporous carbon composites for hydroxylamine and chlorogenic acid

Xin Zhao et al.

ANALYTICA CHIMICA ACTA (2019)

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Review Biotechnology & Applied Microbiology

Recent progress in nanoscale metal-organic frameworks for drug release and cancer therapy

Liangcan He et al.

NANOMEDICINE (2019)

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Article Multidisciplinary Sciences

Comparative study on the catalytic activity of Fe-doped ZrO2 nanoparticles without significant toxicity through chemical treatment under various pH conditions

Hye-in Song et al.

SCIENTIFIC REPORTS (2019)

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Article Polymer Science

Degradation of Metal-Organic Framework Materials as Controlled-Release Fertilizers in Crop Fields

Ke Wu et al.

POLYMERS (2019)

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Article Chemistry, Analytical

Fabrication of porphyrin-based magnetic covalent organic framework for effective extraction and enrichment of sulfonamides

Juan Zhang et al.

ANALYTICA CHIMICA ACTA (2019)

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Article Chemistry, Multidisciplinary

Face-Sharing Archimedean Solids Stacking for the Construction of Mixed-Ligand Metal-Organic Frameworks

Yu-Chen Qiu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal-Organic Frameworks via Mechanochemistry

Bahar Karadeniz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Multidisciplinary Sciences

Wafer-scale synthesis of monolayer two-dimensional porphyrin polymers for hybrid superlattices

Yu Zhong et al.

SCIENCE (2019)

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Review Chemistry, Multidisciplinary

Cyclodextrin-metal-organic framework (CD-MOF): From synthesis to for applications

T. Rajkumar et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2019)

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Review Biochemistry & Molecular Biology

Extraction of Metal Ions with Metal-Organic Frameworks

Natalia Manousi et al.

MOLECULES (2019)

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Article Chemistry, Multidisciplinary

Nano-Biohybrids: In Vivo Synthesis of Metal-Organic Frameworks inside Living Plants

Joseph J. Richardson et al.

SMALL (2018)

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Article Nanoscience & Nanotechnology

Potential Utility of Metal-Organic Framework-Based Platform for Sensing Pesticides

Kumar Vikrant et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Multidisciplinary

pi-Extended Benzoporphyrin-Based Metal-Organic Framework for Inhibition of Tumor Metastasis

Jin-Yue Zeng et al.

ACS NANO (2018)

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Article Chemistry, Multidisciplinary

Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks

Liangliang Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Physical

A metal-organic framework with large 1-D channels and rich -OH sites for high-efficiency chloramphenicol removal from water

Xudong Zhao et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2018)

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Review Chemistry, Inorganic & Nuclear

Shape engineering of metal-organic frameworks

Bardiya Valizadeh et al.

POLYHEDRON (2018)

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Article Chemistry, Physical

The Metal-Organic Framework Collapse Continuum: Insights from Two-Dimensional Powder X-ray Diffraction

Ryan A. Dodson et al.

CHEMISTRY OF MATERIALS (2018)

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Article Multidisciplinary Sciences

Steric paper based ratio-type electrochemical biosensor with hollow-channel for sensitive detection of Zn2+

Li Li et al.

SCIENCE BULLETIN (2017)

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Article Multidisciplinary Sciences

Fluorescence and Magnetic Resonance Dual-Modality Imaging-Guided Photothermal and Photodynamic Dual-Therapy with Magnetic Porphyrin-Metal Organic Framework Nanocomposites

Hui Zhang et al.

SCIENTIFIC REPORTS (2017)

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Article Electrochemistry

Porphyrinic metal-organic framework/macroporous carbon composites for electrocatalytic applications

Duanduan Yin et al.

ELECTROCHIMICA ACTA (2017)

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Article Chemistry, Inorganic & Nuclear

A porphyrin-based metal-organic framework as a pH-responsive drug carrier

Wenxin Lin et al.

JOURNAL OF SOLID STATE CHEMISTRY (2016)

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Article Chemistry, Multidisciplinary

Thermodynamically Guided Synthesis of Mixed-Linker Zr-MOFs with Enhanced Tunability

Shuai Yuan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Multidisciplinary

Shaping of Metal-Organic Frameworks: From Fluid to Shaped Bodies and Robust Foams

Yifa Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Multidisciplinary

Size-Controlled Synthesis of Porphyrinic Metal-Organic Framework and Functionalization for Targeted Photodynamic Therapy

Jihye Park et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Physical

A more efficient way to shape metal-organic framework (MOF) powder materials for hydrogen storage applications

Jianwei Ren et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2015)

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Review Engineering, Environmental

Removal of hazardous organics from water using metal-organic frameworks (MOFs): Plausible mechanisms for selective adsorptions

Zubair Hasan et al.

JOURNAL OF HAZARDOUS MATERIALS (2015)

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Article Chemistry, Physical

Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications

Sameer Patwardhan et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

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Article Chemistry, Multidisciplinary

A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs

Kecheng Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Chemistry, Multidisciplinary

Energy Transfer on Demand: Photoswitch-Directed Behavior of Metal-Porphyrin Frameworks

Derek E. Williams et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Chemistry, Multidisciplinary

A Highly Stable Porphyrinic Zirconium Metal-Organic Framework with shp-a Topology

Dawei Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Editorial Material Chemistry, Multidisciplinary

Activation of metal-organic framework materials

Joseph E. Mondloch et al.

CRYSTENGCOMM (2013)

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Article Chemistry, Multidisciplinary

Construction of Ultrastable Porphyrin Zr Metal-Organic Frameworks through Linker Elimination

Dawei Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Multidisciplinary

A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures

Arnau Carne-Sanchez et al.

NATURE CHEMISTRY (2013)

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Article Chemistry, Multidisciplinary

A Water-Stable Porphyrin-Based Metal-Organic Framework Active for Visible-Light Photocatalysis

Alexandra Fateeva et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

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Article Chemistry, Multidisciplinary

Commercial metal-organic frameworks as heterogeneous catalysts

Amarajothi Dhakshinamoorthy et al.

CHEMICAL COMMUNICATIONS (2012)

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Article Chemistry, Physical

Electrospun fibrous mats as skeletons to produce free-standing MOF membranes

Yi-nan Wu et al.

JOURNAL OF MATERIALS CHEMISTRY (2012)

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Article Chemistry, Multidisciplinary

Reverse Shape Sellectivity in the Liquid-Phase Adsorption of Xylene Isomers in Zirconium Terephthalate MOF UiO-66

Mariana A. Moreira et al.

LANGMUIR (2012)

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Review Chemistry, Multidisciplinary

Rational Design, Synthesis, Purification, and Activation of Metal-Organic Framework Materials

Omar K. Farha et al.

ACCOUNTS OF CHEMICAL RESEARCH (2010)

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Review Chemistry, Physical

Immobilization of halogenated porphyrins and their copper complexes in MCM-41: Environmentally friendly photocatalysts for the degradation of pesticides

M. Silva et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2010)

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Article Materials Science, Ceramics

Metal-Organic Frameworks in Monolithic Structures

Pia Kuesgens et al.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2010)

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Article Chemistry, Multidisciplinary

A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts

Abraham M. Shultz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Article Chemistry, Physical

Direct measurements of absolute concentration and lifetime of singlet oxygen in the gas phase by electron paramagnetic resonance

Keisuke Hasegawa et al.

CHEMICAL PHYSICS LETTERS (2008)

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