Journal
MATTER
Volume 5, Issue 10, Pages 3499-3512Publisher
CELL PRESS
DOI: 10.1016/j.matt.2022.07.010
Keywords
-
Categories
Funding
- Shenzhen Key Laboratory of Functional Aggregate Materials [ZDSYS20211021111400001]
- National Natural Science Foundation of China [21788102]
- Research Grants Council of Hong Kong [16305518, 16307020, C6009-17G, N_HKUST609/19]
- Innovation and Technology Commission [ITC-CNERC14SC01]
- Natural Science Foundation of Guangdong Province [2019B121205002, 2019B030301003]
Ask authors/readers for more resources
This study presents a guest/host system (NL/DCB) with high RTP quantum yield and ultralong lifetime at room temperature. The efficient RTP of the NL/DCB system is mainly attributed to the formation of cluster excitons, which boost the RTP efficiency and allow for fast and ultrasensitive detection of hazardous VOCs.
Room temperature phosphorescence (RTP) materials have attracted wide attention due to their application potential in sensing, data-encryption, bioimaging, and optoelectronic devices. However, improving RTP efficiency and lifetime simultaneously in metal-free systems remains the biggest challenge for realizing their applications. Herein, by exploiting long-lifetime triplets of naphthalene (NL) and intersystem crossing (ISC)-promoting factors from 1,4-dichlorobenzene ( DCB), we unveil a guest/ host system (NL/DCB) with concurrently high RTP quantum yield of >20% and ultralong lifetime of >760 ms ( duration similar to 10 s) at ambient conditions. Based on systematic experimental and theoretical investigations, the underlying mechanism for efficient RTP of NL/DCB is mainly elucidated to be the formation of cluster excitons that boost ISC and triplet population of NL molecules. Meanwhile, we showcase the first example of fast and ultrasensitive detection of a common hazardous VOC via turning on its ultralong afterglow by using NL/DCB RTP, opening another avenue for practical applications of purely organic phosphorescence.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available