Journal
MATTER
Volume 5, Issue 10, Pages 3485-3498Publisher
CELL PRESS
DOI: 10.1016/j.matt.2022.07.009
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Funding
- NSFC [21971203]
- Key Scientific and Technological Innovation Team of Shaanxi Province [2020TD-001]
- Xi'an Municipal Bureau of Science and Technology [201805056ZD7CG40]
- State Key Laboratory for Mechanical Behavior of Materials, Fundamental Research Funds for the Central Universities
- Guangdong Natural Science Funds for Distinguished Young Scholar [2018B030306009]
- Young Elite Scientists Sponsorship Program by CAST [2017QNRC001]
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This study demonstrates the importance of creating a large ground magnetic moment for suppressing the zero-field quantum tunneling of magnetization in single-molecule magnets (SMMs). By using bridging fluoride to create ferromagnetic couplings among the lanthanide ions, the molecule in this study possesses a large ground magnetic moment and exhibits a very hard magnetic hysteresis loop.
Single-molecule magnets (SMMs) have been proposed for ultra-high-density information storage due to prolonged relaxation times below blocking temperature (T-B). However, many SMMs suffer from fast magnetization loss at zero-field regime due to the quantum tunneling of magnetization (QTM) effect. Here we show the creation of large ground magnetic momentum is crucial to suppress zero-field QTM for SMMs. The recipe is to use bridging fluoride, which creates ferromagnetic couplings among the lanthanide ions in the complex [Dy3Cr3(mu(3)-F) (mu(3)-OH)(3)(mdea)(3)(piv)(8)DMF]center dot H2O center dot CH3CN. As such, the molecule owns a large ground magnetic moment of 10:7 mu(B) and is confirmed to be an SMM with T-B of 5 K. More importantly, a very hard magnetic hysteresis loop with a coercive field of 1.3 T and more than 97% remanence is observed up to 0.7 K. Ab initio calculations fully support such observations, rendering the importance of fluorido bridge to suppress zero-field QTM for lanthanide-based SMMs.
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