4.6 Article

Study on the effect of CH4 dissolution on the microstructure of wax crystal in waxy crude oil

Journal

PETROLEUM SCIENCE
Volume 19, Issue 4, Pages 1853-1865

Publisher

KEAI PUBLISHING LTD
DOI: 10.1016/j.petsci.2022.04.007

Keywords

Waxy crude oil; CH4 dissolution; Wax crystal; Rheology; Mechanism

Funding

  1. National Natural Science Foundation of China [51774315, 51574274]
  2. Natural Science Found of Hebei Province [E2020203013]

Ask authors/readers for more resources

This study comprehensively investigated the influence of dissolved methane gas on wax crystals and the rheology of crude oil. Experimental results showed that the behavior of crude oil varied depending on the type of crude oil and the pressure of dissolved CH4.
In this work, the influence of the dissolution of methane (CH4) gas on the wax crystal of waxy crude oil and the effect on the rheology of crude oil by dissolved CH4 were studied comprehensively. A self-deign high-pressure micro visualization device was developed to analyze wax crystals before and after gas dissolution. The crude oil from Shengli and Nanyang was tested by the device under various gas pressures. Results showed that the viscosity, maximum shear stress and equilibrium shear stress of Shengli crude oil decreased with the increasing pressure of the dissolved CH4. Due to the supersaturation of dissolved gas, the viscosity, maximum shear stress and equilibrium shear stress of Nanyang crude oil decreased initially and increased with the increasing pressure of dissolved CH4. The change in rheology of the dissolved gas crude oil can be a combined influence of gas pressure and dissolution mechanisms caused by CH4. Additionally, the wax precipitation point of Shengli crude oil decreased at the saturated dissolution of CH4, while Nanyang crude oil showed an increasing wax precipitation temperature. Notably, the wax precipitation area, number of wax particles, and average diameter of wax crystal in both crude oils gradually decreased with dissolution. However, a saturation of CH4 caused a small amount of precipitation of wax crystals in Nanyang crude oil, and the small wax crystals were aggregated to form the large wax crystals. The dissolution of CH4 gas can affect the wax crystallization process, crystallization ability, and morphology of wax crystals that resulted in significant variation in the rheology of crude oil. (C) 2022 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available