4.8 Article

Negating Na||Na3Zr2Si2PO12 interfacial resistance for dendrite-free and Na-less solid-state batteries

Related references

Note: Only part of the references are listed.
Article Engineering, Environmental

Effective resistance to dendrite growth of NASICON solid electrolyte with lower electronic conductivity

Xinxin Wang et al.

Summary: The study demonstrated that doping lanthanide ions can enhance the ionic conductivity and relative density while reducing the electronic conductivity of NASICON electrolytes, leading to improved resistance to dendrite growth in solid-state lithium/sodium batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Nanoscience & Nanotechnology

Interfacial Engineering with a Nanoparticle-Decorated Porous Carbon Structure on β-Alumina Solid-State Electrolytes for Molten Sodium Batteries

Minyuan M. Li et al.

Summary: A novel anode interface modification on the beta ''-alumina solid-state electrolyte was proposed, improving the wetting behavior of molten sodium in battery applications. Heat treatment formed a porous carbon network with PbOx nanoparticles, leading to stable low-resistance interface for close to 6000 cycles, and achieving a high stable cycling capacity in Na-S cell.

ACS APPLIED MATERIALS & INTERFACES (2022)

Review Chemistry, Physical

Stabilizing Metallic Na Anodes via Sodiophilicity Regulation: A Review

Chenbo Yuan et al.

Summary: This review focuses on the challenges and strategies regarding wetting of sodium in sodium-metal batteries (SMBs). The article provides a general description of the wetting issues encountered in different SMB systems and discusses emerging strategies for improving wetting and stabilizing sodium metal anodes. The review also highlights overlooked aspects and proposes promising areas for further research.

MATERIALS (2022)

Article Chemistry, Physical

A dendrite-suppressed and utilization-improved metallic Li anode enabled by lithiophilic nano-Pb decoration on carbon cloth

Peng Du et al.

Summary: Li metal anodes with uniform nano-Pb decoration on carbon cloth (Pb@CC) achieved ultralong cycle life and low overpotentials, showing great potential for commercial applications.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Multidisciplinary

Ambient-Temperature All-Solid-State Sodium Batteries with a Laminated Composite Electrolyte

Xingwen Yu et al.

Summary: This study introduces a sodium-ion conductive laminated polymer/ceramic-polymer solid-state electrolyte for room-temperature all-solid-state sodium batteries, providing balanced Na+ ion conductivity and a stable electrochemical window. The batteries fabricated with this solid electrolyte exhibit remarkably stable cyclability.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Design Principles of Sodium/Potassium Protection Layer for High-Power High-Energy Sodium/Potassium-Metal Batteries in Carbonate Electrolytes: a Case Study of Na2Te/K2Te

Hai Yang et al.

Summary: The study demonstrates that Na2Te/K2Te can improve Na+/K+ transport and suppress dendrite formation, offering a promising way to stabilize sodium (potassium)-metal anodes.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

A Morphologically Stable Li/Electrolyte Interface for All-Solid-State Batteries Enabled by 3D-Micropatterned Garnet

Rong Xu et al.

Summary: The use of a novel 3D-micropatterned solid-state electrolyte can stabilize the morphology of the Li/SSE interface even under high current density and limited stack pressure, preventing interface degradation.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

All-Solid-State Batteries with a Limited Lithium Metal Anode at Room Temperature using a Garnet-Based Electrolyte

Shaojie Chen et al.

Summary: The new all-solid-state lithium-metal battery (ASSLMB) with an ultralow negative/positive electrode capacity ratio (N/P ratio) shows longer cycling life compared to liquid electrolyte batteries at the same low N/P ratios. The study also investigates the effect of interface layer species on the cycling performance of ASSLMBs.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Intrinsic low sodium/NASICON interfacial resistance paving the way for room temperature sodium-metal battery

Jin An Sam Oh et al.

Summary: This study introduces a simple and cost-effective annealing process to improve the interface between the electrolyte and metallic sodium. The annealed electrolyte shows an extremely small interfacial resistance and high critical current density, providing insight into electrolyte surface preparation and its significance in a sodium-metal solid-state battery.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Review Materials Science, Multidisciplinary

Recent progress of ceramic electrolytes for post Li and Na batteries

Masashi Kotobuki

Summary: Post Li batteries, especially Na battery, have been intensively researched recently due to high cost of Li sources. However, ceramic electrolytes for other post Li batteries such as K, Mg, Ca, Zn, and Al batteries are not well summarized in existing literature. More research is needed in this area to develop all-solid-state post-Li batteries.

FUNCTIONAL MATERIALS LETTERS (2021)

Review Materials Science, Multidisciplinary

NASICON-structured Na ion conductor for next generation energy storage

Qing Huang et al.

Summary: The Na ion conductor with NASICON structure is of great interest for its superior ionic conductivity and stable structures, making it widely employed in various types of batteries. This review covers its structure, composition, properties, and applications for next generation energy storage.

FUNCTIONAL MATERIALS LETTERS (2021)

Article Multidisciplinary Sciences

Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding

Xinxin Wang et al.

Summary: The authors proposed an ultrasound solid welding strategy to improve the contact between Na metal and Na3Zr2Si2PO12 (NZSP) inorganic solid electrolyte, leading to stable Na plating/stripping behavior and lower interfacial impedance. This strategy was also demonstrated to achieve a capacity retention of almost 90% after 900 cycles at room temperature in a Na|NZSP | Na3V2(PO4)(3) full coin cell configuration.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Homogeneous Nat transfer dynamic at Na/Na3Zr2Si2PO12 interface for all solid-state sodium metal batteries

Yongjie Zhao et al.

Summary: The study introduces a grain-boundary engineering strategy to stabilize the Na/Na3Zr2Si2PO12 interface and enhance sodium ion transfer capability at the interface. By mediating the chemical composition at the grain boundary of Na3Zr2Si2PO12 through the addition of sintering additive Na2B4O7, densification sintering at lower temperature is facilitated to boost sodium ion migration. The resulting all-solid-state batteries exhibit excellent cycling performance with enhanced stability and reduced interfacial resistance.

NANO ENERGY (2021)

Article Chemistry, Multidisciplinary

Amorphous-Carbon-Coated 3D Solid Electrolyte for an Electro-Chemomechanically Stable Lithium Metal Anode in Solid-State Batteries

Hua Xie et al.

Summary: The study introduces a novel approach to maintain a stable Li metal | electrolyte interface by depositing amorphous carbon nanocoating on a garnet-type solid-state electrolyte, demonstrating outstanding electro-chemomechanical stability and promoting homogeneity in lithium metal stripping and plating processes. This work suggests that amorphous carbon coatings may be a promising strategy for achieving stable Li metal | electrolyte interfaces and reliable Li metal batteries.

NANO LETTERS (2021)

Article Chemistry, Multidisciplinary

Grain Boundary Design of Solid Electrolyte Actualizing Stable All-Solid-State Sodium Batteries

Chengzhi Wang et al.

Summary: The study proposes a new interphase design for addressing urgent interfacial stability issues in all-solid-state sodium metal batteries. By manipulating the grain boundary phase of a Mg2+-doped Na3Zr2Si2PO12 conductor, a favorable Na3-2 delta Mg delta PO4-dominant interphase is introduced to improve contact with Na metal and act as an electron barrier. This design leads to a significant decrease in interfacial resistance, high cycling stability, and excellent rate capability in all-solid-state Na metal batteries.

SMALL (2021)

Article Chemistry, Physical

A Robust Solid-Solid Interface Using Sodium-Tin Alloy Modified Metallic Sodium Anode Paving Way for All-Solid-State Battery

Jin An Sam Oh et al.

Summary: All-solid-state alkaline metal batteries are considered ideal high energy density storage systems, but require stable physical contact between the anode and solid-state electrolyte. By using a composite anode and enhancing Na+ diffusion kinetics, the tendency to form pores during desodiation can be reduced, leading to stable cycling.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Physical

Recent Progress in Cathode Materials for Sodium-Metal Halide Batteries

Xiaowen Zhan et al.

Summary: Transitioning from fossil fuels to renewable energy sources is crucial for addressing greenhouse gas emissions and climate change. Sodium metal halide (Na-MH) batteries, such as the Na-NiCl2 battery, are considered a promising solution for safe and economical grid-level energy storage. By using lower cost metal halides in the cathode and operating at lower temperatures, new Na-MH batteries have the potential to offer comparable performance at much lower overall costs, providing an exciting alternative technology for widespread adoption of renewables-plus-storage for the grid.

MATERIALS (2021)

Article Chemistry, Physical

Improving Na/Na3Zr2Si2PO12 Interface via SnOx/Sn Film for High-Performance Solid-State Sodium Metal Batteries

Jiayi Yang et al.

Summary: Introducing a SnOx/Sn film successfully improves the interface between Na and NZSP in solid-state batteries, reducing the interfacial resistance significantly and enhancing electrochemical performance. The modified Na||Na symmetric cell cycles over 1500 hours at room temperature with only 40 mV overpotential at 0.1 mA cm(-2).

SMALL METHODS (2021)

Article Chemistry, Physical

Microstructural Tuning of Solid Electrolyte Na3Zr2Si2PO12 by Polymer-Assisted Solution Synthesis Method and Its Effect on Ionic Conductivity and Dielectric Properties

Brahma Prakash Dubey et al.

Summary: This study reveals that the straightforward polymer-assisted solution synthesis (PASS) route is beneficial for developing highly conducting single-phase NASICON-type Na3Zr2Si2PO12 (NZSP), preventing the formation of unwanted secondary phases and increasing the system density. Through X-ray diffraction, field-emission scanning transmission electron microscopy, and other tools, it was found that the PASS method provides better control over the microstructure and conductivity of NZSP samples.

ACS APPLIED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

All solid thick oxide cathodes based on low temperature sintering for high energy solid batteries

Xiang Han et al.

Summary: Solid-state batteries (SSBs) have the potential to improve safety and energy density compared to conventional liquid cells. By utilizing NASICON-type solid electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP) and constructing mixed conductive interphases through low-melting-point liquid sintering, high-loading solid cathodes with improved kinetics have been achieved, showing promising capacity loading up to 6 mA h cm(-2) for LATP/LiCoO2 cathodes and up to 10 mAh cm(-2) for Ni-rich cathodes, leading to cells with energy density exceeding 400 Wh kg(-1).

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Report Stabilizing the Na/Na3Zr2Si2PO12 interface through intrinsic feature regulation of Na3Zr2Si2PO12

Chengzhi Wang et al.

Summary: The microstructure and composition of Na3Zr2Si2PO12 electrolyte significantly impact its interfacial electrochemical behavior, with fine microstructure enhancing ionic conductivity and reducing activation energy. This leads to a stable interface with low interfacial resistance between the Na electrode and the electrolyte ceramic, resulting in notable cycling stability and rate performance at room temperature. Active microstructure control of the electrolyte is crucial in improving Na+ transport capability and accelerating the formation of a kinetically stable interphase at the Na/ceramic electrolyte interface.

CELL REPORTS PHYSICAL SCIENCE (2021)

Article Chemistry, Physical

In situ construction of a stable interface induced by the SnS2 ultra-thin layer for dendrite restriction in a solid-state sodium metal battery

Xinxin Wang et al.

Summary: The interface issue between Na and NASICON solid electrolyte was improved by fabricating aSnS(2) ultra-thin layer on the surface of Na3Zr2Si2PO12 electrolyte, enabling uniform and rapid transfer of charge and Na+ flux. As a result, the Na symmetric cell can stably operate at room temperature with excellent capacity retention ratios and rate performance, driven by the constructed stable interface.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

High performance sodium-sulfur batteries at low temperature enabled by superior molten Na wettability

Minyuan M. Li et al.

Summary: Improving sodium wettability on beta ''-Al2O3 at low temperatures through raising the surface treatment temperature of lead acetate trihydrate has led to high capacity and stable cycling in Na-S cells.

CHEMICAL COMMUNICATIONS (2021)

Article Engineering, Environmental

All-solid-state sodium batteries enabled by flexible composite electrolytes and plastic-crystal interphase

Wei Niu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Review Chemistry, Physical

Electrolytes and Interphases in Sodium-Based Rechargeable Batteries: Recent Advances and Perspectives

Gebrekidan Gebresilassie Eshetu et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Multidisciplinary

Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes

Abhik Banerjee et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Physical

Ultrastable All-Solid-State Sodium Rechargeable Batteries

Jing Yang et al.

ACS ENERGY LETTERS (2020)

Article Materials Science, Multidisciplinary

Reducing Interfacial Resistance by Na-SiO2 Composite Anode for NASICON-Based Solid-State Sodium Battery

Haoyu Fu et al.

ACS MATERIALS LETTERS (2020)

Review Nanoscience & Nanotechnology

Development of solid-state electrolytes for sodium-ion battery-A short review

Yumei Wang et al.

NANO MATERIALS SCIENCE (2019)

Article Chemistry, Physical

Insights into Sodium Ion Transfer at the Na/NASICON Interface Improved by Uniaxial Compression

Yasuhiro Uchida et al.

ACS APPLIED ENERGY MATERIALS (2019)

Article Chemistry, Multidisciplinary

Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries

Yutao Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Physical

A Self-Forming Composite Electrolyte for Solid-State Sodium Battery with Ultralong Cycle Life

Zhizhen Zhang et al.

ADVANCED ENERGY MATERIALS (2017)

Article Chemistry, Physical

Na3Zr2(SiO4)2(PO4) prepared by a solution-assisted solid state reaction

Sahir Naqash et al.

SOLID STATE IONICS (2017)

Review Electrochemistry

Review-Solid Electrolytes in Rechargeable Electrochemical Cells

John B. Goodenough et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

Review Multidisciplinary Sciences

Electrical Energy Storage for the Grid: A Battery of Choices

Bruce Dunn et al.

SCIENCE (2011)