Journal
RSC ADVANCES
Volume 12, Issue 52, Pages 33516-33524Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra04676h
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Funding
- Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University (IMSIU)
- [RP-21-09-71]
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A new one-dimensional perovskite material, 4-BAPC, was successfully synthesized and characterized. The material exhibits stability and high color temperature, making it suitable for various applications in optoelectronic devices.
A one dimensional (1D) perovskite-type (C6H7NBr)(3)[CdBr5] (abbreviated 4-BAPC) was synthesized by slow evaporation at room temperature (RT). 4-BAPC crystalizes in the monoclinic system with the space group P2(1)/c. The 1D inorganic chains are formed by corner sharing CdBr6 octahedra. Thermal measurement shows that 4-BAPC is stable up to 190 degrees C. Optical characterization demonstrates that the grown crystal is an indirect bandgap material with a bandgap value of 3.93 eV, which is consistent with theoretical calculations. The electronic structure, calculated using density functional theory, reveals that the valence band originates from a combination of Br-4p orbitals and Cd-4d orbitals, whereas the conduction band originates from the Cd-5s orbitals. The photoluminescence spectroscopy shows that the obtained material exhibits a broad-band white light emission with extra-high CRI of 98 under lambda(exc) = 380 nm. This emission is mainly resulting from the self-trapped exciton recombinations within the inorganic CdBr6 octahedron, and the fluorescence within the organic conjugated ammonium salt.
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