Ni(ii) immobilized on poly(guanidine-triazine-sulfonamide) (PGTSA/Ni): a mesoporous nanocatalyst for synthesis of imines

Mesoporous materials have been the subject of intense research regarding their unique structural and textural properties and successful applications in various fields. This study reports a novel approach for synthesizing a novel porous polymer stabilizer through condensation polymerization in which Fe3O4 magnetic nanoparticles (Fe3O4 MNPs) are used as hard templates. Using this method allowed the facile and fast removal of the template and mesopores formation following the Fe3O4 MNPs. Different techniques were performed to characterize the structure of the polymer. Based on the obtained results, the obtained mesoporous polymeric network was multi-layered and consisted of repeating units of sulfonamide, triazine, and guanidine as a novel heterogeneous multifunctional support. Afterward, the new nickel organometallic complex was supported on its inner surface using the porous poly sulfonamide triazine guanidine (PGTSA/Ni). In this process, the obtained PGTSA/Ni nanocomposite was used as a heterogeneous catalyst in the synthesis of imines from amines. Since this reaction has an acceptorless dehydrogenation pathway, the hydrogen gas is released as its by-product. The synthesized nanocatalyst was structurally confirmed using different characterization modalities, including FT-IR, SEM, XRD, EDX, TEM, elemental mapping, ICP-AES, BET, and TGA. In addition, all products were obtained in high turnover frequency (TOF) and turnover number (TON). The corresponding results revealed the high selectivity and activity of the prepared catalyst through these coupling reactions. Overall, the synthesized nanocatalyst is useable for eight cycles with no considerable catalytic efficiency loss.

Automated summary

This study presents a novel method for synthesizing a porous polymer stabilizer using Fe3O4 magnetic nanoparticles as templates. The synthesized polymer showed a multi-layered structure and was used as a support for a nickel organometallic complex. The resulting nanocomposite exhibited high selectivity and activity as a heterogeneous catalyst in imine synthesis. The synthesized catalyst could be used for eight cycles without significant loss of catalytic efficiency.