4.6 Article

Ultralow-Supersaturation Al Pretreatment toward Low Dislocation Density and Low Radio Frequency Loss GaN/AlN Epi-Stacks on High-Resistivity Si Substrates

Journal

ACS APPLIED ELECTRONIC MATERIALS
Volume 4, Issue 8, Pages 4113-4118

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.2c00747

Keywords

GaN/AlN/Si; AlN nucleation; Al-Si alloy; parasitic conduction; RF loss

Funding

  1. National Natural Science Foundation of China [61922001, 61927806]
  2. National Key Research and Development Program of China [2021YFB3600901, 2018YFE0125700]
  3. Beijing Municipal Science and Technology Project [Z211100004821007]
  4. Key Research and Development Program of Guangdong Province [2020B010171002]

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An ultralow-supersaturation Al pretreatment approach has been proposed to achieve low threading dislocation density and low RF loss GaN/AlN layer stacks on Si substrates. The approach eliminates the Al-Si liquid alloy and results in a sharp AlN/Si interface. It also enlarges the size of AlN nucleation islands, reducing the generated threading dislocations. As a result, a crack-free GaN layer can be obtained directly on the low dislocation density AlN layer without the need for transition layers.
An ultralow-supersaturation Al pretreatment approach has been proposed to achieve low threading dislocation (TD) density and low radio frequency (RF) loss GaN/AlN layer stacks on Si substrates. By employing this approach, the Al-Si liquid alloy is eliminated, and a sharp AlN/Si interface is obtained. In addition, the size of the AlN nucleation islands is enlarged and thus the TDs generated from the coalescence of the islands are reduced even at a low growth temperature. Owing to the low TD density AlN layer, a 1.5 mu m crack-free GaN layer can be achieved directly on this AlN layer and no transition layers are required. The full width at half maximum values are as low as 390 and 440 arcsec for the GaN (002) and (102) diffractions, respectively. Owing to a low growth temperature and short growth time, the RF loss of the epi-stack is as low as 0.29 dB/mm at 10 GHz. This work shows great potential for the fabrication of high-quality and low-loss GaN-on-Si RF devices.

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