Journal
CHEMELECTROCHEM
Volume 3, Issue 12, Pages 2017-2020Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201600396
Keywords
electrocatalysis; liposome; nanoimpacts; nanostructures; redox inactivity
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Funding
- European Research Council under the European Union's Seventh Framework Programme (ERC) [[320403]]
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We show the electrochemical determination of attomole glutathione contents within single individual liposomes at low overpotentials through mediated electron transfer by using copper (II) as a catalyst for the oxidation of liposomal glutathione. A titration-like behaviour of individual liposomes was observed when impacting with the electrode to quantify the content within single liposomes. The nanoimpacts titration strategy allows the characterisation of nanoparticles containing redox-inactive molecules at the single-nanoparticle level.
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