4.5 Review

Perovskite as a Cathode Material: A Review of its Role in Solid-Oxide Fuel Cell Technology

Journal

CHEMELECTROCHEM
Volume 3, Issue 4, Pages 511-530

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201500382

Keywords

cathodes; disordered perovskites; ordered perovskites; oxygen reduction reaction; solid oxide fuel cells

Funding

  1. Mid-career Researcher Program - Korea Government Ministry of Science, ICT and Future Planning [2013R1A2A2A04015706]
  2. Basic Science Research Program - Ministry of Education through the National Research Foundation of Korea [2010-0021214]
  3. National Research Foundation of Korea [2010-0021214, 2013R1A2A2A04015706] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Solid oxide fuel cells (SOFCs) are characterized by low pollution, and are therefore the best alternative both for distributed energy sources and large-scale integration. Fuel flexibility, including hydrocarbons, is the main advantage of SOFCs. For the successful introduction of SOFC technology to the market, reduced temperature operation at 600-800 degrees C is an essential factor. One of the important issues for the reduced temperature operation is to get rid of stability issues while maintaining a certain level of performance. Therefore, the development of alternative materials such as perovskite cathodes is essential to create not only practically acceptable performance, but also to ensure the highly reliable and stable operation of the resulting SOFCs. This review provides a critical and comprehensive survey on the perovskite materials for SOFC cathodes and suggests effective and stable alternatives for the realiable operation of SOFCs.

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