Journal
CHEMELECTROCHEM
Volume 3, Issue 6, Pages 892-895Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201600033
Keywords
disordered rock-salt structure; intercalation cathode; lithium-ion batteries; low temperature; oxyfluorides
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Funding
- KNMF
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At -10 degrees C and 26 mAg(-1), Li2Cr0.2V0.8O2F can deliver a stable high capacity of 250 mAhg(-1) (or 690 Whkg(-1)) over 60 cycles. Even at -20 degrees C and a current density of 106 mAg(-1), it still delivers a steady capacity and specific energy of about 160 mAhg(-1) and 400 Whkg(-1), respectively, over 100 cycles. Superior performance of Li2Cr0.2V0.8O2F over Li2VO2F and Li2CrO2F is related to its structural stability and electronic properties.
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