4.5 Article

Sodium Carboxymethylcellulose Derived Oxygen-Rich Porous Carbon Anodes for High-Performance Lithium/Sodium-Ion Batteries

Journal

CHEMELECTROCHEM
Volume 4, Issue 3, Pages 500-507

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201600577

Keywords

battery anodes; carboxymethylcellulose; lithium-ion batteries; mesoporous materials; structure-activity relationships

Funding

  1. National Natural Science Foundation of China [21506131]
  2. Science and Technology Support Program of Sichuan Province [2015RZ0057, 2016RZ0052]

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Sodium carboxymethylcellulose (CMC), which contains large amounts of carboxymethyl and hydroxy groups, has been used as an oxygen-containing carbon precursor to prepare oxygen-rich porous carbon (OPC) in a silica-template process. CMC can be mixed homogeneously with the silica template because of its excellent water solubility and viscosity, which is one of the key reasons for the successful preparation of OPC. The obtained OPC possesses some micropores, many mesopores with different sizes, a large specific surface area of 1792.6m(2)g(-1), and a high oxygen content of 8.63wt%, and exhibits superb dual functionality as anodes for lithium-ion and sodium-ion batteries.

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