Journal
CATALYSTS
Volume 6, Issue 10, Pages -Publisher
MDPI AG
DOI: 10.3390/catal6100161
Keywords
porous organic tubes; heterogeneous catalysis; Suzuki coupling in water
Categories
Funding
- National Natural Science Foundation of China [21276191]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20120032120083]
- Natural Science Foundation of Tianjin, China [16JCQNJC06200]
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It is highly desirable to design functionalized supports in heterogeneous catalysis regarding the stabilization of active sites. Pd immobilization in porous polymers and henceforth its application is a rapidly growing field. In virtue of its' scalable synthesis and high stability in reaction conditions, amorphous polymers are considered an excellent scaffold for metal mediated catalysis, but the majority of them are found as either agglomerated particles or composed of rough spheres. Owing to several important applications of hollow organic tubes in diverse research areas, we aimed to utilize them as support for the immobilization of Pd nanoparticles. Pd immobilization in nanoporous polymer tubes shows high activity in Suzuki cross coupling reactions between aryl halides and sodium phenyl trihydroxyborate in water, which deserves environmental merit.
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