4.1 Article

Cellulose Microbeads: Toward the Controlled Release of Nutrients to Plants

Journal

ACS AGRICULTURAL SCIENCE & TECHNOLOGY
Volume 2, Issue 2, Pages 340-348

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsagscitech.1c00233

Keywords

Zn fertilization; maize; slow release; sustainability; agriculture 4.0

Funding

  1. Sao Paulo Research Foundation (FAPESP) [2015/19121-8, 2015/05942-0, 2018/13401-7]
  2. UK's Research England GCRF institutional award
  3. UK EPSRC [EP/L016354/1]
  4. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior.Brasil (CAPES) [001]
  5. Brazilian National Council for Scientific and Technological Development (CNPq) [306185/2020-2]

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Slow-release fertilizers are a viable solution to address pollution caused by conventional fertilizers. This study reports the synthesis and properties of a zinc fertilizer composed of cellulose microbeads loaded with aqueous ZnSO4. The results suggest that these microbeads can provide efficient nutrient supply.
The use of conventional fertilizers is associated with pollution due to leaching and a mismatch between release rates and crop requirements for optimal development. Slow-release fertilizers could address both problems. Here, the synthesis and properties of a zinc fertilizer composed of cellulose microbeads loaded with aqueous ZnSO4 are reported for the first time. UV-vis spectrophotometry showed that the beads immersed in water released all Zn2+ in about 30 min, regardless of the initial Zn2+ concentration. In two sandy substrates (a pure sand and a sandy loam substrate), microprobe X-ray fluorescence spectroscopy determined Zn2+ release from beads to the substrate corresponding to count rates of about 0.115 mm min(-1) s(-1), irrespective of the substrate and with a low sensitivity for the water content, except in a very dry range. These results indicate that these microbeads could represent a practical and sustainable solution for efficient nutrient supply in agriculture.

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