4.8 Article

Graphene-Coated PVDF/PAni Fiber Mats and Their Applications in Sensing and Nanogeneration

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 33, Pages 38162-38171

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c0904538162

Keywords

forcespinning; conductive polymer; sensing; graphene; nanogeneration

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This study investigates the sensing and energy generation performance of PVDF/PAni fiber mat systems made by the forcespinning method with and without graphene coating. The graphene-coated nanocomposites show improved output voltage and current performance, as well as better sensitivity and voltage generation for temperature and vibration sensing. The graphene-coated composite also shows potential as a water tide energy harvesting piezoelectric nanogenerator.
Forcespinning is a powerful technique to produce fiber systems with suitable properties for a vast array of applications. This study investigates the sensing and energy generation performance of PVDF/PAni fiber mat systems made by the forcespinning method with and without graphene coating. The developed fiber mats were coated with graphene nanoflakes by drop-casting. The graphene-coated nanocomposites show an average output voltage of 75 mV (peak-to-peak), which is 300% higher compared to bare fiber mats, and an output current of 24 mA (peak-to-peak) by gentle finger pressing. Moreover, graphene-coated PVDF/PAni showed a volume conductivity of 1.2 ?? 10???7 S/cm and was investigated as a promising system for temperature (5 times better sensitivity than normal fiber mat), vibration (2 times better voltage generation), and airflow sensing. The graphene-coated composite has been further investigated as a water tide energy harvesting piezoelectric nanogenerator, with the system generating ???40 mV for a synthetic ocean wave with a flow rate of 30 mL/min. In the future, graphene-coated nanofiber mats can be a solution for low-powered sensors and to harvest blue energy and vibration energy. Superscript/Subscript Available

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