Effects of alkali treatment on properties of willow bark fiber as potential fillers for polymer composites

In this work, willow fiber was extracted from willow inner bark and modified with alkali solution of various concentrations, temperature and time. The morphology, surface functional group, crystal and thermal stability were investigated by using a scanning electron microscopy, a Fourier transform infrared spectroscopy, an X-ray powder diffractometer, and a simultaneous thermal analyzer, respectively. The acid (H2SO4, 2 ml/l) extraction procedure removed the hemicellulose and part of lignin from willow bark, cleared the aggregation of WB, kept the crystal structure of willow fiber, dramatically increased the crystal length of fiber (from 18.46 to 30.15 nm), and enhanced the onset degradation temperature (from 262.23celcius to 297.62celcius) and chemical reactivity (DTG: from 0.57%/s to 0.84%/s). The alkali treatment further removed lignin from willow fiber, smoothed the fiber surface, increased the intensity of cellulose ( I 002 ) from 646 counts to 1292 counts, and lengthened the crystal length from 30.15 to 41.84 nm. Varying the alkali treating condition, the crystal index and thermal stability reached to the climax at 60celcius of treating temperature and 7 h treating time. The treated willow fiber may have potential applications to composite with polymer, and to be used in pharmaceutical field as additives.

Automated summary

In this study, willow fiber was modified using acid and alkali treatment. Acid treatment removed lignin and improved thermal stability and reactivity, while alkali treatment further removed lignin and improved fiber surface and crystallinity.