4.8 Article

High-performance alloy model-based ternary small molecule solar cells

Journal

NANO ENERGY
Volume 30, Issue -, Pages 276-282

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2016.10.021

Keywords

Small molecular solar cell; Ternary strategy; Alloy mode; Charge carrier transport

Funding

  1. Fundamental Research Funds for the Central Universities [2016YJS161]
  2. National Natural Science Foundation of China [61377029, 61564003]
  3. Guangxi Natural Science Foundation [2015GXNSFGA139002]

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There are two crucial tasks for achieving high-performance organic solar cells: increasing photon harvesting and realizing the optimized morphology of active layers. Here, two small molecules DRCN5T and DR3TSBDT as donors and PC71BM as acceptor were employed to fabricate ternary small molecule solar cells (SMSCs). The optimized ternary SMSCs delivered a power conversion efficiency of 10.16%, which was higher than that of binary SMSCs. In addition to enhanced photon harvesting, the two donors with good compatibility prefer to form alloy state in ternary active layer, resulting in efficient hole transport and continuously tunable open circuit voltage.

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