4.6 Article

A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus

Journal

JOURNAL OF MATERIALS CHEMISTRY B
Volume 4, Issue 36, Pages 5975-5979

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6tb01966h

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Funding

  1. Fundacio Caixa Castello/UJI [P1-1B2015-76]
  2. Russian Foundation for Basic Research for research [16-33-60016]
  3. Spanish Ministry of Science and Innovation, Spain [CTQ2013-48767-C3-2-R]
  4. European Regional Development Fund

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The ability of a hexanuclear molybdenumcluster, [Mo6I8(CH3COO)(6)](2-), to carry out, upon irradiation, singlet oxygen mediated photocatalytic oxygenation reactions has been tested. This complex has been also supported on a solid polymeric matrix, yielding an immobilized photosensitizer with remarkable photostability and recyclability. Preliminary studies of antibacterial photoinactivation of Staphylococcus aureus have been conducted, with positive results.

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