Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 26, Pages 10110-10113Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta03257e
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Funding
- EPSRC [EP/K008102/2, EP/M01486X/1]
- EPSRC [EP/K008102/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/M01486X/1, EP/K008102/1, EP/K008102/2] Funding Source: researchfish
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Greatly enhanced microporosity is obtained for the amorphous porous polymers produced from the AlCl3-mediated coupling of aromatic hydrocarbons by using dichloromethane as the reaction solvent. A polymer of average BET surface area = 2435 m(2) g(-1) was obtained reproducibly from 1,3,5-triphenylbenzene with the additional porosity being provided as ultramicroporosity as demonstrated by very high CO2 adsorption at 273 K/1 bar.
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