Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 20, Pages 7555-7559Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta01828a
Keywords
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Funding
- Max Planck Society
- China Scholarship Council (CSC) [201406240010]
- Excellence Initiative (DFG/GSC) of the graduate school of excellence MAINZ (Materials Science in Mainz) [266]
- DAAD
- CAPES
- CNPq
- Fonds der Chemischen Industrie (FCI)
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Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.
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