4.6 Article

Ni2P-CoP hybrid nanosheet arrays supported on carbon cloth as an efficient flexible cathode for hydrogen evolution

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 43, Pages 16992-16999

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta07704h

Keywords

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Funding

  1. National Basic Research Program of China [2016YFA0202603, 2015CB932304]
  2. Natural Science Foundation of Guangdong Province [S2013020012833, 2016A010104004]
  3. Fundamental Research Fund for the Central Universities [16lgjc67]

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Here we report a new type of Ni2P-CoP hybrid nanosheet array (HNSAs) supported on carbon cloth (CC) (Ni2P-CoP HNSAs/CC) as an efficient flexible cathode for the hydrogen evolution reaction (HER). This synthesized Ni2P-CoP HNSAs/CC shows excellent electrocatalytic performance for the HER in both acid and alkaline solutions compared with Ni2P/CC and CoP/CC cathodes that have been considered to be good candidates for the HER. The significantly improved electrocatalytic performance of Ni2P-CoP HNSAs/CC can be attributed to the special surface effects of hybrid nanosheet arrays and synergistic effects between Ni2P and CoP. The Ni2P-CoP HNSAs/CC shows excellent flexibility and exhibits unchangeable electrochemical performance under the various distorted states, such as bending and twisting sates.

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