Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 35, Pages 13603-13610Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta03687b
Keywords
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Funding
- NSF of China [21203022, 21261001, 21361001]
- Natural Science Foundation of Jiangxi Province of China [20143ACB20002]
- Young scientist training program of Jiangxi Province of China [20142BCB23018]
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The development of simple and fast methods for the production of metal-oxide nanoparticle (NP)@MOF (metal-organic framework) composites is still a big challenging task. Herein, we demonstrate that certain functionalized MOF surfaces are suitable for such usage, leading to the fabrication of Fe2O3-NP@MOF composites in just an instant. To our best knowledge, this should represent the simplest and fastest approach among all established approaches for the preparation of metal-oxide-NP@MOF composites. The same features for the MOFs selected in this work are viewed as the key drivers for such formations and, accordingly, a mechanism for the surface coordination interaction between the MOF surface and the Fe3+ ions via a typical 'phenol-Fe3+' coloration reaction is suggested.
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