4.6 Article

Cross-linked single-walled carbon nanotube aerogel electrodes via reductive coupling chemistry

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 15, Pages 5385-5389

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta10311h

Keywords

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Funding

  1. Deanship of Scientific Research at King Abdulaziz University [D-1-434]
  2. EPSRC [EP/L001896/1]
  3. EPSRC [EP/K01658X/1, EP/G007314/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/L001896/1, EP/G007314/1, EP/K01658X/1] Funding Source: researchfish

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Single-walled carbon nanotube (SWCNT) anions can be cross-linked by a dielectrophile to form covalent, carbon-bonded organogels. Freeze-drying produces cryogels with low density (2.3 mg cm(-3)), high surface area (766 m(2) g(-1)), and high conductivity (9.4 S m(-1)), showing promise as supercapacitor electrodes. Counterion concentration controls debundling, grafting ratio, as well as all the resulting properties.

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