Journal
JOURNAL OF MEMBRANE SCIENCE LETTERS
Volume 2, Issue 2, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.memlet.2022.100029
Keywords
Metal; Organic Frameworks; Mixed Matrix Membranes; MOF surface defects; MOF; polymer adhesion; Gas transport; Molecular simulations
Categories
Funding
- King Abdullah University of Science and Technology (KAUST) [CCF 1972]
- GENCI-CINES [A0120907613]
Ask authors/readers for more resources
Engineering structure defects at MOF surfaces can enhance the adhesion between MOF and polymer, accelerate gas transport, and improve the selectivity of membranes.
MOF/polymer adhesion in Mixed Matrix Membranes (MMMs) has been mainly enhanced so far via MOF and/or polymer functionalization to strengthen the interactions between the two components. This strategy, albeit ef-fective, is generally accompanied by a drop in the permeability and/or selectivity performance of the MMMs. In this contribution, engineering structure defects at the MOF surfaces is proposed as an effective route to create pockets that immobilize part of the polymer chain, which is of crucial importance both to avoid plasticization issues and to enhance the MOF/polymer affinity while overcoming the adhesion/performance trade-off in MMMs. This engineered interfacial interlocking structure also serves as a bridge to accelerate the gas transport from the polymeric region towards the MOF pore entrance. This concept is showcased with a model MMM made of the prototypical UiO-66 MOF and the glassy Polymer of Intrinsic Microporosity-1 (PIM-1) and tested using CO2, CH4 and, N 2 as guest species. Our computational findings reveal that a defective UiO-66 MOF surface improves the MOF/PIM-1 adhesion and contributes to accelerate the interfacial gas transport of the slender molecules CO2 and N 2 and in a lesser extent of the spherical molecule CH4. This translates into a selective enhancement of the CO2 transport once combined with CH4 which paves the ways toward promising perspective for pre-combustion CO2 capture.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available