4.6 Article

Cooperative electrochemical water oxidation by Zr nodes and Ni-porphyrin linkers of a PCN-224 MOF thin film

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 43, Pages 16818-16823

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta05877a

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences [DE-SC0012446]
  2. U.S. Department of Energy (DOE) [DE-SC0012446] Funding Source: U.S. Department of Energy (DOE)
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [1531834] Funding Source: National Science Foundation

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Here, we demonstrate a new strategy for cooperative catalysis and proton abstraction via the incorporation of independent species competent in the desired reactivity into a metal-organic framework (MOF) thin film. The highly porous MOF, designated as PCN-224-Ni, is constructed by Zr-oxo nodes and nickel(II) porphyrin linkers. Films of PCN-224-Ni were grown in situ on FTO and were found to electro-chemically facilitate the water oxidation reaction at near neutral pH.

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