4.6 Article

Cloud-like graphene nanoplatelets on Nd0.5Sr0.5CoO3-delta nanorods as an efficient bifunctional electrocatalyst for hybrid Li-air batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 6, Pages 2122-2127

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta08493h

Keywords

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Funding

  1. Mid-career Researcher Program [NRF-2013R1A2A2A04015706, NRF-2015R1A2A1A10055886]
  2. Creative Research Initiative (CRI) Program through National Research Foundation of Korea - Ministry of Science, ICT and Future Planning
  3. Research Fund of UNIST (Ulsan National Institute of Science Technology) [1.150120.01]

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With the recognition of metal-air batteries as promising candidates for clean and efficient energy storage, the development of inexpensive and effective bifunctional catalysts for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) has become one of the most important topics in this field. Herein, we designed new composite catalysts consisting of a nanorod type Nd0.5Sr0.5CoO3-delta (NSC) perovskite and edge-iodinated graphene nanoplatelets (IGnPs) as bifunctional catalysts for ORR and OER. Interestingly, the simple application of ultrasonication endowed the catalyst with a fascinating morphology comprising cloud-like IGnPs on NSC nanorods (NSC@IGnP). Benefiting from the unique morphological features, NSC@IGnP provides superior bifunctional activities toward both ORR and OER, remarkable cell performance, and exceptionally high stability for hybrid Li-air batteries.

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