4.6 Article

Influence of steric bulk on the oxidative stability of phenolate-based magnesium-ion battery electrolytes

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 2, Pages 368-371

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta07479g

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Funding

  1. National Science Foundation [DMR-1253347]
  2. Division Of Materials Research
  3. Direct For Mathematical & Physical Scien [1253347] Funding Source: National Science Foundation

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A compilation of electrolytes within the standard (PhOMgCl)-Ph-R and AlCl3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. Most notably, 2,4,6-trimethylphenol-based solutions exhibited high conductivity (2.56 mS cm(-1)) and compatibility with the Chevrel-phase Mo6S8 intercalation cathode (over 200 h cycle time at C/10 current).

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