Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 31, Pages 12152-12157Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta04859e
Keywords
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT) [15H03591, 15K13287, 15H2202, 16H06507]
- Advanced Low Carbon Technology Research and Development Program (ALCA) for Specially Promoted Research for Innovative Next Generation Batteries (SPRING), Japan Science and Technology Agency (JST)
- Grants-in-Aid for Scientific Research [15H00870, 15H02202, 16H06507, 15K13287, 15H03591] Funding Source: KAKEN
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Pt nanoparticles monodispersed in an ionic liquid (IL), which can be readily prepared by magnetron sputtering onto an IL, are a key material for tailoring highly durable Pt nanoparticle-supported carbon electrocatalysts, e.g., Pt nanoparticle-supported single-walled carbon nanotubes (Pt-SWCNTs) and Vulcan (R) XC-72 (Pt-Vulcan (R)), for the electrochemical oxygen reduction reaction. The durability largely surpasses that of one of the commercially available Vulcan (R) XC-72-based catalysts, TEC10V30E. The differences were very obvious from the results of electrochemical measurements, ex situ TEM observation, and in situ SEM/STEM observation; that is, considerable damage by carbon corrosion was recognized for the TEC10V30E, but it was not the case for the Pt-SWCNT and Pt-Vulcan (R). The unexpected high durability should be due to the suppression of carbon corrosion by the ionic liquid thin layer that exists between the Pt nanoparticles and carbon support.
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