Journal
ECOMAT
Volume 5, Issue 2, Pages -Publisher
WILEY
DOI: 10.1002/eom2.12293
Keywords
Co single-atom catalyst; hydrogen evolution; MXene substrates; oxygen evolution; water splitting
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Decorating single atoms of transition metals on MXenes enhances the electrocatalytic properties of the resulting composites. In this study, cobalt single atoms were anchored onto several commonly used MXene substrates, and the electrocatalytic behavior and mechanisms were systematically studied. The Co@V2CTx composite showed lower overpotentials for oxygen and hydrogen evolution reactions compared to other composites, making it comparable to commercial noble metal electrocatalysts. The enhanced catalytic performance of Co@V2CTx was attributed to optimized electronic structure and accelerated catalytic kinetics. This study sheds light on the origins and guidelines for designing efficient MXene-based electrocatalysts.
Decorating single atoms of transition metals on MXenes to enhance the electrocatalytic properties of the resulting composites is a useful strategy for developing efficient electrocatalysts, and the mechanisms behind this enhancement are under intense scrutiny. Herein, we anchored Co single atoms onto several commonly used MXene substrates (V2CTx, Nb2CTx and Ti3C2Tx) and systematically studied the electrocatalytic behavior and the mechanisms of oxygen and hydrogen evolution reactions (OER and HER, respectively) of the resulting composites. Co@V2CTx composite displays an OER overpotential of 242 mV and an HER overpotential of 35 mV at 10 mA cm(-2) in 1.0 M KOH electrolyte, which is much lower than for Co@Nb2CTx and Co@Ti3C2Tx, making it comparable to the commercial noble metal Pt/C and RuO2/C electrocatalysts. The experimental and theoretical results point out that the enhanced bifunctional catalytic performance of CO@V2CTx benefits from the stronger hybridization between Co 3d and surface terminated O 2p orbitals which optimized the electronic structure of Co single atoms in the composite. This, in turn, results in lowering the OER and HER energy barriers and acceleration of the catalytic kinetics in case of the Co@V2CTx composite. The advantage of Co@V2CTx was further validated by its high overall water splitting performance (1.60 V to deliver 10 mA cm(-2)). Our study sheds light on the origins of the catalytic activity of single transition metals atoms on MXene substrates, and provides guidelines for designing efficient bifunctional MXene-based electrocatalysts.
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